Are there settings in Photoshop CS6 to confirm and deselect for example a text frame when pressing escape?
By default escape cancels the editing.
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Use the Enter key.
Not Return or ESC keys.
Adobe logic is that ESC means "never mind" or "cancel" and never "commit".
As @BillyKerr points out, Adobe did add a preference option to alter the default behavior for text editing in more recent versions, but that is not going to be helpful for CS6.