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How to Create Rounded Corner Hexagon in photoshop using polygon tool ?
With the Polygonal Tool selected, click the little gear icon on the Control Bar a and then check the Smooth Corners option.
Photoshop CC or CS6:
Photoshop CS5 or CS4:
You may also need to adjust the "Star" options....
i have a idea, try this
create Hexagon, add thick border from style as shown in image,
and follow the instruction 2 and 3