Right now I have a AI file, and there are some images used in it , the problem is , how to export all of them? Thanks a lot for helping.
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You appear to be using a legacy version of Illustrator.
In Illustrator CC you can highlight embedded images in the Links Panel and choose
Unembed... fromt eh Links Panel Menu which will bring up the Save As dialog window allowing you to save the image separately.
If the image is indeed a link, you would highlight it in the Links Panel and choose
Edit original... to open the original image in the appropriate application...
This is why I say you are working with an older version if Illustrator. Your Links Panel shows the images as embedded, However, you do not have the options possible in Illustrator CC.
If none of the above is possible... simply drag the .ai file to Photoshop and open it there. Then crop and save the images you need.