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I'd use a Curves adjustment to create a solarization effect.
Then you could use a Hue and Saturation adjustment to increase the saturation and alter the colours as required.
0
This effect could be achieved with a gradient map:
Pick an image:
Add a gradient map layer and add your colors. Use the stops between the colors to decide where you want your colors to end up or how posterized you want it to look:
You get something like this. I'm sure you could do better 😃
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